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Anisotropic Release of the Residual Zero-point Entropy in the Spin Ice Compound Dy2Ti2O7: Kagome-ice Behavior

机译:自旋冰中残余零点熵的各向异性释放   化合物Dy2Ti2O7:Kagome-ice行为

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摘要

We report the specific heat and entropy of single crystals of the spin icecompound Dy2Ti2O7 at temperatures down to 0.35 K. We apply magnetic fieldsalong the four characteristic directions: [100], [110], [111] and [112].Because of Ising anisotropy, we observe anisotropic release of the residualzero-point entropy, attributable to the difference in frustrationdimensionality. In the high magnetic field along these four directions, theresidual entropy is almost fully released and the activation entropy reachesRln2. However, in the intermediate field region, the entropy in fields alongthe [111] direction is different from those for the other three fielddirections. For the [111] direction the frustration structure changes from thatof three-dimensional(3D) pyrochlore to that of two-dimensional(2D) Kagome-likelattice with constraint due to the ice rule, leading to different values ofzero-point entropy.
机译:我们报道了在低至0.35 K的温度下自旋冰化合物Dy2Ti2O7的单晶的比热和熵。我们沿四个特征方向施加磁场:[100],[110],[111]和[112]。各向异性,我们观察到残余零点熵的各向异性释放,这归因于挫折维数的差异。在沿这四个方向的高磁场中,剩余熵几乎被完全释放,并且激活熵达到Rln2。但是,在中间场区域中,沿[111]方向的场中的熵与其他三个场方向的熵不同。对于[111]方向,受阻结构从三维(3D)烧绿石转变为二维(2D)Kagome样格,受冰规则的约束,导致零点熵值不同。

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